有机功能材料创新团队成立于2021年，团队目前由王以寿（团队负责人）、汪小钢、郝东艳、高兰昌、苟杏杏、范超超、拜武7位博士组成，主要以有机化学为基础，围绕共价有机框架材料的合成与应用，形成了“有机功能材料”为特色的研究方向。团队在Angew. Chem., Int. Ed.、Sci. China. Chem.、Org. Lett.、Chem. Mater.等国际TOP期刊和权威期刊发表高水平学术论文40余篇，授权专利6件。获批陕西省科学技术厅项目5项、陕西省基础科学研究院项目2项、商洛学院科研项目10余项。
1.部分研究项目：
[1]基于COFs“阱”的Pd纳米颗粒的制备以增强其在醇的选择性氧化反应中的稳定性和催化活性.项目编号2023-JC-QN-0100，陕西省科学技术厅青年项目。
[2]基于镍负载的共价有机框架催化剂的精准构筑提高聚烯烃分子量和极性单体插入比的研究.项目编号22JHQ008，陕西省基础科学研究院青年项目。
[3]改性废弃胶原蛋白合成两性聚合物及其对胶原纤维柔顺行为的研究.项目编号2022JQ-141，陕西省科学技术厅青年项目。
[4]金属/路易斯酸协同催化卡宾前体对苯胺的N-H键插入串联分子内亲核环化反应研究.项目编号22JHQ010，陕西省基础科学研究院青年项目。
[5]基于COFs“阱”铜纳米颗粒的可控制备以提高电化学还原CO2反应中的选择性和催化活性.项目编号2024JC-YBQN-0081，陕西省科学技术厅青年项目。
[6]基于9,10-二炔/烯蒽核心有机小分子及配位驱动金属超分子自组装体的[4 + 2]光氧化反应研究.项目编号2024-JC-YBQN-0133，陕西省科学技术厅青年项目。
[7]导向策略下过渡金属/可见光协同催化谐二氟烯烃碳氟官能化反应研究.项目编号2024JC-YBQN-0131，陕西省科技厅青年项目。
2.部分科研成果：
(1)Wang,Y.-S.;Yuan,X.-N.;Gou,X.-X.;Song, X.-T.;Wang,X.;Guo,L.;Liu,Y.;Qiao,C.; Zhou,C.;Han,Y.-F.Sci. China. Chem.2024, https://doi.org/10.1007/s11426-024-2401-5(SCI一区,IF = 10.4).
(2)Wang,X.;Szostak,M.Synthesis of Functionalized Indoles by Iridium-Catalyzed N–H Insertion Cascade: Nucleophilic Cyclization of Naphthylamines witha-Diazocarbonyl Compounds. The Journal of Organic Chemistry,2024,(Accepted)
(3)Wang, Y.-S.;Bai, S.; Wang, Y.-Y.; Han, Y.-F.Controllable Synthesis of Polyimidazolium Macrocycles Basedon Metal⁃N⁃heterocyclic Carbene Templates. Chinese J. Inorg. Chem.2024, 40,221–231.
(4)Fan C.C.;Liu Y.;Gong Q.Y.;Zhou C.S.;Qiao C.F. Synthesis and Characterization of SiO2/nGO/Fe3O4/SeQDs Nanoparticles as Potential Nanocarriers in Drug Delivery Systems. Langmuir,2024, 40, 12792-12801. (SCI二区, IF = 4.3)
(5)Hao,D.;Su,R.;W,C.Properties of Epoxy Modified Starch Tanning Agent Combined with Aluminium Salt.Journal of the society of leather technologists and chemists,2024,108,28-35.
(6)Hao,D.;Guo, X.; Zhu,X.Progress in synthesis, modification, characterization and applications of hyperbranched polyphosphate polyesters.Designed Monomers and Polymers,2024, 27, 62-86.
(7)Wang, Y.-S.;Li, H.; Zhang, L.; Bai, S.; Wang, Y.-Y.; Han, Y.-F.N-Heterocyclic Carbene-Stabilized Platinum Nanoparticles within a Porphyrinic Nanocage for Selective Photooxidation.Sci. China. Chem.2023,66, 778−782(SCI一区,IF = 10.4).
(8)Hao, D.;Zhu,X.;Hao,D. Synthesis of Ionic Liquid-Based Amphiphilic PolymerSurfactant and its Application in Leather Fatliquoring.Journal of the society of leather technologists and chemists,2023,107,60-65.
(9)Fan, C.C.;Wang,Y.;Zhao,J.;Zhao,Y.X.;Yang,D.;Li,B.Y.;Yu,L.;Yang,X.-J.;Wu B. Reversible [4 + 2] Photooxygenation in Anion-Coordiantion-Driven-Assembled A2L2-Type Complexes. Inorg. Chem.,2022, 61, 2198-2203. (SCI一区, IF = 5.4)
(10)Wang, Y.-S.;Wang, Y.-Y.; Han, Y.-F.Phase-Mediated Controllable Intra- and Intermolecular Photocycloadditions Assisted by Supramolecular Templates.Sci. China. Chem.2022,65,1129–1133(SCI一区,IF = 10.4).
(11)Gao, L.; Hao, C.; Ma, R.; Chen, J.; Zhang, G.; Chen, Y. Synthesis and Biological Evaluation of a New Class of Multi-target Heterocycle Piperazine Derivatives as Potential Antipsychotics.RSC Advances,2021,11, 16931−16941.
(12)Gao, L.; Hao, C.; Chen, J.; Ma, R.; Zheng, L.; Wu, Q.; Liu, X.; Liu, B. F.; Zhang, G.; Chen, Y.; Jin, J.. Discovery of a New Class of Multi-Targetheterocycle Piperidine Derivatives as Potential Antipsychotics with Pro-cognitive Effect,Bioorganic & Medicinal Chemistry Letters,2021,40, 127909.
(13)Gao, L.; Yang, Z.; Xiong, J.; Hao, C.; Ma, R.; Liu, X.; Liu, B. F.; Jin, J.; Zhang, G.; Chen, Y. Design, Synthesis and Biological Investigation of Flavone Derivatives as Potential Multi-Receptor Atypical Antipsychotics.Molecules,2020,25, 4107.
(14)Wang,X.;Zhang,J.;He,Y.;Chen,D.;Wang, C.;Yang,F.;Wang,W.;Ma,Y.;Szostak,M. Ruthenium(II)-Catalyzed Ortho-C-HAlkylayion of Naphthylamines with Diazo Compounds for Synthesis of 2,2-Disubstituted Extended 3-Oxindoles in Water,Org. Lett.,2020,22, 5287-5192.
(15)Hao,D.;Wang,X.;Liu,X.A Novel Eco-friendly Imidazole Ionic Liquids Based Amphoteric Polymers for High Performance Fatliquoring in Chromium-free Tanned Leather Production.Journal of hazardous materials.2020,339,123048.
(16)Gou,X.-X.;Liu,T.;Wang,Y.-Y.;Han,Y.-F.Ultrastable and Highly Catalytically Active N-Heterocyclic-Carbene-Stabilized Gold Nanoparticles in Confined Spaces.Angew. Chem. Int. Ed.2020,59, 16683-16689.
(17)Gou, X.-X.;Peng,J.-X.;Das,R.;Wang,Y.-Y.;Han,Y.-F. On/offFluorescenceEmissionInduced byEncapsulation,Exchange andReversibleEncapsulation of a BODIPY-Guest inSelf-AssembledOrganometallicCages.Dalton Trans.,2019,48, 7236-7241.
(18)Wang, X.; Zhang, J.; Chen, D.; Wang, B.; Yang, X.; Ma, Y.; Szostak, M. Rh(III)-Catalyzed C-H Amidation of 2-Arylindoles with Dioxazolones: A Route to Indolo[1,2-c]quinazolines, Organic Letters, 2019, 21, 7038-7043. (一区top)
(19)Wang, Y.-S.;Bai, S.; Wang, Y.-Y.; Han, Y.-F.Process-Tracing Study on the Post-Assembly Modification of Poly-NHC-Based Metallosupramolecular Cylinders with Tunable Aggregation-Induced Emission.Chem. Commun.2019,55, 13689−13692(SCI二区, IF =6.065).
(20)Wang, Y.-S.;Feng, T.; Wang, Y.-Y.;Hahn, F. E.;Han, Y.-F.Homo- and Heteroligand Poly-NHC Metal Assemblies: Synthesis byNarcissistic and Social Self-Sorting.Angew. Chem.,Int. Ed.2018,57, 15767−15771(SCI一区, IF =16.823).
3.指导学生情况：
2023年，指导学生在第四届全国师范生微课大赛获二等奖、第十四届“挑战杯”大学生课外学术科技作品竞赛校级三等奖、化材学院职业生涯规划大赛一等奖1项、三等奖1项、第九届陕西省大学生化学实验邀请赛一等奖1项、二等奖1项、三等奖1项、大学生创新训练计划校级立项、第九届中国国际“互联网＋”大学生创新创业大赛陕西省银奖。
2024年，指导学生获得第四届全国大学生化学实验设计创新大赛校级二等奖、第十七届节能减排社会实践与科技竞赛校级二等奖、第五届全国师范生微课大赛优秀奖、大学生创新训练计划省级立项、中国国际“互联网+”大学生创新创业大赛省级三等奖、商洛学院中国国际大学生创新大赛铜奖、第十二届挑战杯陕西省大学生创业计划竞赛铜奖。
